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Ultrasensitive Detection of Biomarkers by Using a Molecular Imprinting Based Capacitive Biosensor

Ultrasensitive Detection of Biomarkers by Using a Molecular Imprinting Based Capacitive Biosensor

Published on: February 16, 2018

A path to soluble molecularly imprinted polymers.

Abhilasha Verma¹, George M Murray²

¹Department of Mechanical, Aerospace and Biomedical Engineering, Center for Laser Applications, University of Tennessee Space Institute, 411 B.H. Goethert Parkway, Tullahoma, TN 37388, USA. averma@utsi.edu.

Journal of Functional Biomaterials

|June 24, 2014

Summary

This summary is machine-generated.

Molecular imprinting creates selective polymer binding sites. New soluble, star-shaped polymers offer faster, more accessible molecularly imprinted polymers (MIPs) for trace analysis.

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Area of Science:

Polymer Chemistry
Analytical Chemistry
Materials Science

Background:

Molecular imprinting creates selective binding sites in polymers for specific molecules.
Metal ions as chromophores enhance selectivity in molecularly imprinted polymers (MIPs).
Conventional MIPs suffer from insolubility and slow diffusion, limiting their application.

Purpose of the Study:

To review methods for trace determination of organophosphates using MIPs.
To explore the development of soluble and processable MIPs.
To overcome the limitations of conventional MIPs in device integration and response time.

Main Methods:

Utilizing controlled free radical polymerization techniques to create pseudo-living polymers.
Synthesizing block copolymers with crosslinkable substituents.
Forming star polymers with crosslinkable mers for soluble, processable MIPs.

Main Results:

Soluble, star-shaped MIPs exhibit rapid responses due to shorter diffusion distances.
These novel MIPs are processable and suitable for device integration.
Review of methods for trace organophosphate determination using MIPs.

Conclusions:

Soluble, star-shaped MIPs offer significant advantages over conventional MIPs.
Controlled polymerization techniques enable the creation of advanced MIP architectures.
These advancements facilitate highly sensitive and selective trace analysis.