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Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron
Published on: August 12, 2019
Syntheses of cyclotriveratrylene analogues and their long elusive triketone congeners
Nathan E Wright1, Adel M ElSohly, Scott A Snyder
1Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027, United States.
Abstract:
Although interest in cyclotriveratrylene and its analogues has been significant, limitations in the ability to adjust its structure fully have hampered studies into their complete range of properties. A unique strategy to synthesize a previously unobtainable cyclotriveratrylene analogue and a procedure which adjusts the inner methylene bridges of that material to a triketone is reported. A second triketone synthesis and computational studies indicate the parameters needed for success.
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