pH-responsive inorganic-organic hybrid supramolecular hydrogels with jellyfish-like switchable chromic luminescence
Haibing Wei1, Nan Shi, Jinlong Zhang
1Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China. jz10@pku.edu.cn xhwan@pku.edu.cn.
Abstract:
A unique type of novel supramolecular hybrid hydrogel based on the co-assembly of the anionic polyoxometalate and the cationic ABA triblock copolymer via electrostatic interaction was reported to show jellyfish-like switchable chromic luminescence. The hydrogel undergoes reversible sol-gel transition in response to pH changes, and simultaneously exhibits an unprecedented luminescent chromism from weak green to strong white.
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