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Updated: Apr 27, 2026

15N CPMG Relaxation Dispersion for the Investigation of Protein Conformational Dynamics on the µs-ms Timescale
Published on: April 19, 2021
Model to interpret pulsed-field-gradient NMR data including memory and superdispersion effects
Marie-Christine Néel1, Daniela Bauer2, Marc Fleury2
1Université d'Avignon et des Pays de Vaucluse, UMR 1114 EMMAH, F-84018 Avignon Cedex, France.
We developed a new model for interpreting Nuclear Magnetic Resonance (NMR) velocimetry data. This versatile tool quantifies dispersion in porous media, improving flow analysis in various conditions.
Area of Science:
- Geophysics
- Physical Chemistry
- Fluid Dynamics
Background:
- Quantitative interpretation of Nuclear Magnetic Resonance (NMR) velocimetry data is crucial for understanding fluid flow in porous media.
- Existing models may not fully capture complex flow behaviors, including intermittent low velocities and rare high-velocity events.
Purpose of the Study:
- To propose a versatile model for the quantitative interpretation of NMR velocimetry data.
- To incorporate mechanisms of random arrests and long displacements into dispersion theory.
- To provide analytical expressions for NMR signals based on subordinated Lévy processes.
Main Methods:
- Utilized the Lagrangian form of dispersion theory with mobile/immobile tracer particles.
- Incorporated independent random arrests and rare long displacements to simulate complex flow.
- Derived analytical expressions for pulsed-field-gradient NMR signals.
- Applied the model to NMR data from water flow in a homogeneous grain pack column.
Main Results:
- The model provides a framework for quantitative interpretation of NMR velocimetry data.
- Analytical expressions for NMR signals were derived based on subordinated Lévy processes.
- Demonstrated the model's utility in quantifying dispersion for single- and two-phase flow.
Conclusions:
- The proposed model offers a versatile approach for interpreting NMR velocimetry data.
- It effectively quantifies dispersion in porous media by accounting for complex flow dynamics.
- The model is applicable to both single- and two-phase flow conditions.
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