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Updated: Apr 27, 2026

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Bethe free-energy approximations for disordered quantum systems
1DISAT and Center for Computational Sciences, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.
Abstract:
Given a locally consistent set of reduced density matrices, we construct approximate density matrices which are globally consistent with the local density matrices we started from when the trial density matrix has a tree structure. We employ the cavity method of statistical physics to find the optimal density matrix representation by slowly decreasing the temperature in an annealing algorithm, or by minimizing an approximate Bethe free energy depending on the reduced density matrices and some cavity messages originated from the Bethe approximation of the entropy. We obtain the classical Bethe expression for the entropy within a naive (mean-field) approximation of the cavity messages, which is expected to work well at high temperatures. In the next order of the approximation, we obtain another expression for the Bethe entropy depending only on the diagonal elements of the reduced density matrices. In principle, we can improve the entropy approximation by considering more accurate cavity messages in the Bethe approximation of the entropy. We compare the annealing algorithm and the naive approximation of the Bethe entropy with exact and approximate numerical simulations for small and large samples of the random transverse Ising model on random regular graphs.
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