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Updated: Apr 26, 2026

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
Published on: May 29, 2018
Novel method for the fabrication of a charge-transfer complex crystal by photoirradiation
Masaki Matsuda1, Miki Nishi, Shoko Koga
1Graduate School of Science and Technology, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555 (Japan), Fax: (+81) 96-342-3372. masaki@sci.kumamoto-u.ac.jp.
Abstract:
A novel method for the fabrication of a charge-transfer complex crystal was developed. Photoirradiation of a solution of TPP[Co(tbp)(CN)(2)] and TPP[Co(Pc)(CN)(2)] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN)(2)](2), which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc.

