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Updated: Apr 26, 2026
Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation
Published on: August 28, 2017
A molecular "screw-clamp": accelerating click reactions in miniemulsions
Evandro M Alexandrino1, Philipp Buchold, Manfred Wagner
1Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany. wurm@mpip-mainz.mpg.de.
Abstract:
The interface as a "screw clamp": the copper-free 1,3-dipolar azide-alkyne cycloaddition at the interface of nanodroplets in miniemulsions was studied in detail by NMR spectroscopic methods. The reaction at the oil-water interface proved to exhibit higher rate constants, increased molecular weights and high regioregularity compared to the reaction in solution.
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