Vertically aligned carbon nanofiber nanoelectrode arrays: electrochemical etching and electrode reusability

Vertically aligned carbon nanofibers in the form of nanoelectrode arrays were grown on nine individual electrodes, arranged in a 3 × 3 array geometry, in a 2.5 cm² chip. Electrochemical etching of the carbon nanofibers was employed for electrode activation and enhancing the electrode kinetics. Here, we report the effects of electrochemical etching on the fiber height and electrochemical properties. Electrode regeneration by amide hydrolysis and electrochemical etching is also investigated for electrode reusability.