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Updated: Apr 26, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Polycyclic aromatic hydrocarbons obtained by lateral core extension of mesogenic perylenes: absorption and
Joachim Vollbrecht1, Harald Bock, Christian Wiebeler
1Center for Optoelectronics and Photonics Paderborn, Universität Paderborn, Warburger Strasse 100, 33098 Paderborn (Germany); Centre de Recherche Paul Pascal (CRPP), CNRS, Universite Bordeaux, 33600 Pessac (France).
Abstract:
Bilaterally extended perylenes were synthesized, characterized, and used to create organic light-emitting devices. A detailed investigation of the electronic and optical properties, and a comparison of perylene derivatives and compounds with unilaterally and bilaterally extended aromatic cores, reveal unexpected changes of the absorption spectrum, which are in agreement with simulations based on DFT.
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