Novel open-framework europium silicates prepared under high-temperature and high-pressure conditions
Wei Liu1, Ying Ji, Xinjian Bao
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun, 130012, P. R. China. liuxy@jlu.edu.cn.
Abstract:
Two new europium silicates, Na15Eu3Si12O36 (denoted as 1) and K2EuSi4O10F (denoted as 2), were successfully synthesized under high-temperature and high-pressure conditions, and structurally characterized by single-crystal and powder X-ray diffraction (XRD). The single-crystal XRD analysis of 1 reveals that its structure is based on [Si6O18]n(12n-) cyclosilicate anions that are built from six SiO4 tetrahedra sharing two of their four O corners with each other. Such [Si6O18]n(12n-) cyclosilicate anions are linked via EuO6 octahedra to form a three-dimensional (3D) framework containing 6-membered ring channels delimited by the SiO4 tetrahedra and EuO6 octahedra along the [010] direction. The structure of 2 consists of infinite tubular chains of corner-sharing SiO4 tetrahedra, which are further linked together via corner sharing O atoms by infinite chains of EuO4F2 octahedra forming a 3-D framework that contains 8-ring and 6-ring channels along the [010] direction. The photoluminescence properties of 1 and 2 were also investigated.
