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Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity
Elena Madrid1, Yuanyang Rong, Mariolino Carta
1Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY (UK).
Angewandte Chemie (International Ed. in English)
|August 13, 2014
Abstract:
A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.

