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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
One-pot consecutive catalysis by integrating organometallic catalysis with organocatalysis
Samaresh Chandra Sau1, Sudipta Raha Roy, Swadhin K Mandal
1Department of Chemical Sciences, Indian Institute of Science Education and Research-Kolkata, Mohanpur 741252 (India) http://www.iiserkol.ac.in/∼swadhin.mandal/index.htm.
Abstract:
The present study integrates two types of catalysis, namely, organometallic catalysis and organocatalysis in one reaction pot. In this process, the product of the first catalytic cycle acts as catalytic component for next catalytic cycle. The abnormal N-heterocyclic carbene-copper-based organometallic catalyst acts as an efficient catalyst for a click reaction to provide triazole, which, in turn, acts as an efficient organocatalyst for different organic transformations, for example, aza-Michael addition and multicomponent reactions, in a consecutive fashion in the same reaction pot.
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