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Updated: Apr 25, 2026
Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry
Published on: June 8, 2022
Spectroscopic, crystal structural and electrochemical studies of zinc(II)-Schiff base complex obtained from
Kamel Ouari1, Sabrina Bendia1, Jean Weiss2
1Laboratoire d'Electrochimie, d'Ingénierie Moléculaire et de Catalyse Rédox (LEIMCR), Faculté de Technologie, Université Sétif-1, DZ-19000 Sétif, Algeria.
Abstract:
Mononuclear zinc(II) complex, [Zn(II)L], where L is a dianionic ligand, has been synthesized and characterized by elemental analysis, electronic, IR and NMR [(1)H, (13)C, DEPT, (1)H-(1)H COSY, ROESY, HSQC and HMBC] spectroscopic techniques. Structural analysis of the complex by single crystal X-ray crystallography shows the presence of a distorted square planar coordination geometry (NNOO) of the metal center. The crystal of the title complex C28H18N2O2Zn belongs to the orthorhombic system with space group Pmn21. Electrochemical behavior of the Zn(II)L complex has been investigated by cyclic voltammetry on glassy carbon and platinum electrodes in DMF at 100 mV/s scan rate.
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