Related Experiment Video

Updated: Apr 25, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

3.4K

Infinite dilution partial molar volumes of platinum(II) 2,4-pentanedionate in supercritical carbon dioxide

Chang Yi Kong1, Tomoya Siratori2, Toshitaka Funazukuri3

  • 1Department of Applied Chemistry and Biochemical Engineering, Graduate School of Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan; Research Institute of Green Science and Technology, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan.

Journal of Chromatography. A
|August 30, 2014
PubMed

Keywords:
Chromatographic impulse response methodPartial molar volumePlatinum(II) 2,4-pentanedionateRetention factorSupercritical carbon dioxideSupercritical fluid chromatography

More Related Videos

A Salt-Templated Synthesis Method for Porous Platinum-based Macrobeams and Macrotubes13:08

A Salt-Templated Synthesis Method for Porous Platinum-based Macrobeams and Macrotubes

Published on: May 18, 2020

8.9K
Activating Molecules, Ions, and Solid Particles with Acoustic Cavitation14:22

Activating Molecules, Ions, and Solid Particles with Acoustic Cavitation

Published on: April 11, 2014

14.7K

Related Concept Videos

π Molecular Orbitals of 1,3-Butadiene01:24

π Molecular Orbitals of 1,3-Butadiene

Conjugated dienes have lower heats of hydrogenation than cumulated and isolated dienes, making them more stable. The enhanced stabilization of conjugated systems can be understood from their π molecular orbitals.
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the...
8.6K
¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)01:20

¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)

When proton-coupled carbon-13 spectra are simplified by a broadband proton decoupling technique, structural information about the coupled protons is lost. Distortionless enhancement by polarization transfer (DEPT) is a technique that provides information on the number of hydrogens attached to each carbon in a molecule. While the DEPT experiment utilizes complex pulse sequences, the pulse delay and flip angle are specifically manipulated. The resulting signals have different phases depending on...
1.3K
The Small x Assumption02:20

The Small x Assumption

If a reaction has a small equilibrium constant, the equilibrium position favors the reactants. In such reactions, a negligible change in concentration may occur if the initial concentrations of reactants are high and the Kc value is small. In such circumstances, the equilibrium concentration is approximately equal to its initial concentration. This estimation can be used to simplify the equilibrium calculations by assuming that some equilibrium concentrations are equal to the initial...
43.8K
Applications of the Ideal Gas Law: Molar Mass, Density, and Volume03:43

Applications of the Ideal Gas Law: Molar Mass, Density, and Volume

The volume occupied by one mole of a substance is its molar volume. The ideal gas law, PV = nRT, suggests that the volume of a given quantity of gas and the number of moles in a given volume of gas vary with changes in pressure and temperature. At standard temperature and pressure, or STP (273.15 K and 1 atm), one mole of an ideal gas (regardless of its identity) has a volume of about 22.4 L — this is referred to as the standard molar volume.
64.0K
π Molecular Orbitals of the Allyl Cation and Anion01:18

π Molecular Orbitals of the Allyl Cation and Anion

An allyl group is a three-carbon conjugated system where the sp³-hybridized allylic carbon is bonded to a CH=CH2 group via a single bond. Allyl anions can be obtained by treating propene with a strong base that can deprotonate methyl groups. Allyl cations are formed as intermediates during substitution reactions involving allylic halides. In both cases, the hybridization of the allylic carbon changes from sp3 to sp2, giving rise to a carbon chain with three sp2-hybridized carbons, each...
3.4K
Molecular Orbital Theory II03:51

Molecular Orbital Theory II

Molecular Orbital Energy Diagrams
21.6K