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Updated: Apr 24, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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CHR-insertion (R=H, CH3) into cyclohexyl-substituted silsesquioxanes: reactivity and decomposition studies

Antony J Ward1, Rebecca A Lesic, Keith Fisher

  • 1Laboratory of Advanced Catalysis for Sustainability, School of Chemistry F11, University of Sydney, Sydney 2006, (Australia), Fax: (+61) 2 9351 3329.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|September 3, 2014
PubMed
Summary

Polyhedral oligomeric silsesquioxanes (POSS) reveal novel silica surface reactivities. A specific POSS structure (a6b0) exhibited enhanced reactivity, including CH2-insertion, offering new insights for heterogeneous catalysis.

Keywords:
atmospheric pressure chemical ionisationcollision-induced dissociationmass spectrometrysiloxanessilsesquioxanes

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