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Updated: Apr 24, 2026

Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
Published on: October 15, 2019
Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex
Suzanne McMahon1, Jonathan Rochford, Yvonne Halpin
1School of Chemical Sciences, Dublin City University, Dublin 9, Ireland. mary.pryce@dcu.ie.
Abstract:
Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.
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