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Updated: Apr 23, 2026

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
Published on: February 11, 2016
Perovskite oxide nanosheets with tunable band-edge potentials and high photocatalytic hydrogen-evolution activity
Kazuhiko Maeda1, Miharu Eguchi, Takayoshi Oshima
1Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-NE-2 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan). maedak@chem.titech.ac.jp.
Abstract:
Perovskite nanosheets of HCa(2-x)Sr(x)Nb3O10 and HCa2Nb(3-y)Ta(y)O10 with controlled band-edge potentials were prepared. They worked as highly efficient heterogeneous photocatalysts for H2 evolution from a water/methanol mixture under band-gap irradiation. The activity was found to depend on the composition. The highest activity was obtained with HCa2Nb2TaO10 nanosheets, recording an apparent quantum yield of approximately 80% at 300 nm, which is the highest value for a nanosheet-based photocatalyst reported to date.
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