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Nonvolatile RRAM cells from polymeric composites embedding recycled SiC powders
Anna De Girolamo Del Mauro1, Giuseppe Nenna, Riccardo Miscioscia
1UTTP-NANO, ENEA , Piazzale E. Fermi 1, 80055 Portici, Italy.
Langmuir : the ACS Journal of Surfaces and Colloids
|September 27, 2014
Summary
Recycled silicon carbide (SiC) powders from tires enable resistive switching in polymer composites. This breakthrough demonstrates a novel memory effect in electronic devices, paving the way for sustainable electronics.
Area of Science:
- Materials Science
- Nanotechnology
- Polymer Science
Background:
- Silicon carbide (SiC) is a crucial material in electronics.
- Tire waste presents a significant environmental challenge.
- Recycling processes can recover valuable materials from waste.
Purpose of the Study:
- To synthesize silicon carbide (SiC) powders from end-of-life tires.
- To investigate the properties of SiC powders and their derived composite structures.
- To evaluate the potential of SiC-polymer composites in electronic memory devices.
Main Methods:
- Patented recycling process for SiC powder synthesis.
- Characterization using Dynamic Light Scattering, Raman Spectroscopy, SEM, and X-ray Diffraction.
- Fabrication and testing of two-terminal polymer composite devices with coplanar contacts.
Main Results:
- Successfully synthesized SiC powders from recycled tires.
- Characterization confirmed powder properties and composite structure.
- Demonstrated resistive switching behavior in PMMA-based composite devices.
- Quantified memory effect through read-write-erase measurements, showing distinct level separation and persistence.
Conclusions:
- Recycled SiC powders from tires are viable for electronic applications.
- PMMA-SiC composites exhibit a promising memory effect.
- This research offers a sustainable route for electronic materials and waste valorization.

