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Confirming a predicted selection rule in inelastic neutron scattering spectroscopy: the quantum translator-rotator H2
Minzhong Xu1, Mónica Jiménez-Ruiz2, Mark R Johnson2
1Department of Chemistry, New York University, New York, New York 10003, USA.
Abstract:
We report an inelastic neutron scattering (INS) study of a H2 molecule encapsulated inside the fullerene C60 which confirms the recently predicted selection rule, the first to be established for the INS spectroscopy of aperiodic, discrete molecular compounds. Several transitions from the ground state of para-H2 to certain excited translation-rotation states, forbidden according to the selection rule, are systematically absent from the INS spectra, thus validating the selection rule with a high degree of confidence. Its confirmation sets a precedent, as it runs counter to the widely held view that the INS spectroscopy of molecular compounds is not subject to any selection rules.
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