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Updated: Apr 23, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Synthesis, crystal structures, and catalytic oxidation properties of oxidovanadium(V) complexes with hydrazone and
Abstract:
Two new oxidovanadium(V) complexes with hydrazone ligands and hydroxamate ligands were synthesized and characterized by IR and (1)H NMR spectroscopy, elemental analysis and single crystal X-ray diffraction. The coordination sphere of each V atom is octahedral, constructed from three donor atoms of the hydrazone ligand, two donor atoms of the hydroxamate ligand, and one oxido oxygen. Both complexes show effective catalytic oxidation properties for the oxidation of cyclohexene, cyclopentene and benzyl alcohol using H(2)O(2) as primary oxidant.
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