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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Lithiated sulfoxides: α-sulfinyl functionalized carbanions

Gerd Ludwig1, Tobias Rüffer, André Hoppe

  • 1Institute of Chemistry, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Straße 2, D-06120 Halle, Germany. dirk.steinborn@chemie.uni-halle.de.

Dalton Transactions (Cambridge, England : 2003)
|October 11, 2014
PubMed
Summary

This study details the synthesis of novel alpha-sulfinyl functionalized organolithium compounds using alkyl aryl sulfoxides and n-BuLi-TMEDA. These compounds exhibit unique structural features and undergo diastereoselective reactions with carbonyl compounds.

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