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Updated: Apr 22, 2026

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
Published on: May 27, 2018
Intermolecular Casimir-Polder forces in water and near surfaces
Priyadarshini Thiyam1, Clas Persson2, Bo E Sernelius3
1Department of Materials Science and Engineering, Royal Institute of Technology, SE-100 44 Stockholm, Sweden.
Abstract:
The Casimir-Polder force is an important long-range interaction involved in adsorption and desorption of molecules in fluids. We explore Casimir-Polder interactions between methane molecules in water, and between a molecule in water near SiO(2) and hexane surfaces. Inclusion of the finite molecular size in the expression for the Casimir-Polder energy leads to estimates of the dispersion contribution to the binding energies between molecules and between one molecule and a planar surface.
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