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Updated: Apr 21, 2026

Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems
Published on: April 28, 2016
Characterizing the chiral index of a single-walled carbon nanotube
1Center for Nanochemistry, Beijing National Laboratory for Molecular Sciences, Key Laboratory for the Physics and Chemistry of Nanodevices, State Key Laboratory for Structural, Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, P.R. China.
Abstract:
The properties of single-walled carbon nanotubes (SWCNTs) mainly depend on their geometry. However, there are still formidable difficulties to determine the chirality of SWCNTs accurately. In this review, some efficient methods to characterize the chiral indices of SWCNTs are illuminated. These methods are divided into imaging techniques and spectroscopy techniques. With these methods, diameter, helix angle, and energy states can be measured. Generally speaking, imaging techniques have a higher accuracy and universality, but are time-consuming with regard to the sample preparation and characterization. The spectroscopy techniques are very simple and fast in operation, but these techniques can be applied only to the particular structure of the sample. Here, the principles and operations of each method are introduced, and a comprehensive understanding of each technique, including their advantages and disadvantages, is given. Advanced applications of some methods are also discussed. The aim of this review is to help readers to choose methods with the appropriate accuracy and time complexity and, furthermore, to put forward an idea to find new methods for chirality characterization.
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