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Microstructural changes in copper-graphite-alumina nanocomposites produced by mechanical alloying
Ivan Rodrigues1, Mafalda Guedes2, Alberto C Ferro3
11Instituto Superior Técnico,Universidade de Lisboa,Av. Rovisco Pais,1049-001 Lisboa,Portugal.
Summary
High-energy milling produced nanostructured copper composites with uniformly dispersed graphite and alumina nanoparticles. This indicates potential for enhanced conductivity, strength, and thermal stability in advanced materials.
Area of Science:
- Materials Science
- Nanotechnology
- Composite Materials
Background:
- Nanostructured materials offer enhanced properties.
- Copper-matrix composites are of interest for various applications.
- High-energy milling is a method for producing advanced materials.
Purpose of the Study:
- To investigate the microstructural evolution of nanostructured copper-matrix composites.
- To evaluate the effect of graphite and alumina addition on copper.
- To understand the influence of milling time on composite characteristics.
Main Methods:
- Planetary ball milling of copper-graphite-alumina and copper-graphite powders.
- Characterization using field emission gun scanning electron microscopy/energy-dispersive spectroscopy.
- Analysis via Raman spectroscopy, X-ray diffraction, and particle size analysis.
Main Results:
- Homogeneous distribution of graphite and alumina nanoparticles in the copper matrix was achieved.
- Copper crystallite size reduced to 15 nm after 16 h of milling.
- Milling media contamination increased significantly after 8 h.
Conclusions:
- Efficient dispersion and bonding of nanoparticles in the copper matrix were successful.
- The produced composites show promise for high conductivity, strength, and thermal stability.
- Optimized milling parameters are crucial for achieving desired microstructures and minimizing contamination.
Keywords:
mechanical alloying
