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Updated: Apr 21, 2026

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Direct photo-hydroxylation of the Zr-based framework UiO-66
Jordi Aguilera-Sigalat1, Alyssa Fox-Charles, Darren Bradshaw
1School of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, UK. D.Bradshaw@soton.ac.uk.
Abstract:
We describe the direct post-synthetic hydroxylation of UiO-66 through the photogeneration of hydroxyl radicals. Three approaches have been investigated, and levels of conversion up to 77% have been observed within 48 h.
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