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Updated: Apr 21, 2026

Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells
Published on: March 19, 2017
Stable and low-cost mesoscopic CH3NH3PbI2 Br perovskite solar cells by using a thin poly(3-hexylthiophene) layer as a
Meng Zhang1, Miaoqiang Lyu, Hua Yu
1Nanomaterials Centre, School of Chemical Engineering, The University of Queensland, St Lucia, Qld 4072 (Australia).
Abstract:
Mesoscopic perovskite solar cells using stable CH3 NH3 PbI2 Br as a light absorber and low-cost poly(3-hexylthiophene) (P3HT) as hole-transporting layer were fabricated, and a power conversion efficiency of 6.64 % was achieved. The partial substitution of iodine with bromine in the perovskite led to remarkably prolonged charge carrier lifetime. Meanwhile, the replacement of conventional thick spiro-MeOTAD layer with a thin P3HT layer has significantly reduced the fabrication cost. The solar cells retained their photovoltaic performance well when they were exposed to air without any encapsulation, presenting a favorable stability. The combination of CH3 NH3 PbI2 Br and P3HT may render a practical and cost-effective solid-state photovoltaic system. The superior stability of CH3 NH3 PbI2 Br is also promising for other photoconversion applications.
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