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Trion-induced negative photoconductivity in monolayer MoS2
C H Lui1, A J Frenzel2, D V Pilon1
1Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Physical Review Letters
|November 1, 2014
Summary
In doped monolayer molybdenum disulfide (MoS2), optical excitation unexpectedly decreased conductivity. This occurred due to photoexcited carriers forming trions, which increased effective mass and reduced electrical conduction.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Optoelectronics
Background:
- Optical excitation usually increases semiconductor conductivity.
- Monolayer molybdenum disulfide (MoS2) is a 2D semiconductor with unique electronic properties.
Purpose of the Study:
- Investigate the effect of optical excitation on conductivity in doped MoS2.
- Understand the underlying mechanisms of observed conductivity changes.
Main Methods:
- Ultrafast optical-pump terahertz-probe spectroscopy.
- Utilized doped monolayer molybdenum disulfide (MoS2) as the material system.
Main Results:
- Observed a significant transient decrease in conductivity upon optical excitation.
- Conductivity reduced to 30% of equilibrium value at high pump fluence.
- Identified trion formation (bound electron-hole states) as the cause.
Conclusions:
- Photoexcited carriers interacting with doping-induced charges form trions.
- Increased carrier effective mass due to trions leads to reduced conductivity.
- Demonstrates anomalous optical-electrical behavior in 2D materials driven by many-body interactions.
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