Evolution of amorphous selenium nanoballs in silicone oil and their solvent induced morphological transformation
Arun Kumar Sinha1, Anup Kumar Sasmal, Shyamal Kumar Mehetor
1Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, India. tpal@chem.iitkgp.ernet.in.
Chemical Communications (Cambridge, England)
|November 4, 2014
Abstract:
Selenium generally exhibits preferential habitual 1D growth as a result of redox reactions of selenium compounds. Commercial Se powder melts in silicone oil under refluxing conditions and upon subsequent cooling evolve amorphous Se nanoballs (SNBs). Further ultrapure crystalline 1D Se grows from SNBs due to solvent mediated oriented attachment.
