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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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Methyl/phenyl attraction by CH/π interaction in 1,2-substitution patterns.

Henri Brunner1, Takashi Tsuno, Gábor Balázs

  • 1Institut für Anorganische Chemie, Universität Regensburg , 93040 Regensburg, Germany.

The Journal of Organic Chemistry
|November 6, 2014
PubMed
Summary

In organic compounds with 1,2-Me,Ph substitution, methyl groups form CH/π bonds with phenyl rings, causing characteristic tilting. This interaction shortens specific atomic distances, influencing molecular geometry and stability.

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