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Removal of amoxicillin from wastewater by self-made Polyethersulfone membrane using nanofiltration
Ahmad Moarefian1, Hossein Alizadeh Golestani2, Hooman Bahmanpour3
1Department of Chemical Engineering, College of Science, Shahrood Branch, Islamic Azad University, Shahrood, Iran.
Abstract:
The present study investigated the performance of a self-made nanofiltration (NF) membrane for the removal of antibiotics from wastewater under changing operating conditions such as pH, initial feed concentration, operating pressure, and temperature. Amoxicillin (AMX) was used as one of the commonly prescribed antibiotics. A self-made NF membrane containing Polyethersulfone (PES), and Polyvinylpyrrolidone (PVP) was modified with Polyethylene glycol hexadecyl ether (Brij®58) surfactant. The self-made membrane was characterized by water contact angle, zeta potential, ATR-FTIR spectroscopy, and scanning electronic microscope (SEM). The obtained results showed that the AMX rejection and permeation flux by the self-made membrane varied from 56.49% to 99.09% and from 15.14 L/m(2)h to 110.29 L/m(2)h, respectively. The AMX rejection decreased at a higher level of initial feed concentration while other operating parameters such as pH, operating pressure, and temperature had a negligible effect on the removal of AMX from wastewater by the self-made NF membrane. The highest removal rate was achieved under conditions of pH 9.0, a temperature of 298 K, an operating pressure of 2 MPa, and an initial feed concentration of 20 ppm. According to the research findings, the self-made NF membrane is recommended for the removal of AMX to a considerable extent at low initial feed concentrations.
Insights
This study developed a novel nanofiltration (NF) membrane for removing amoxicillin (AMX) from wastewater. The membrane effectively removes AMX, especially at lower concentrations, showing its potential for antibiotic removal.
Area of Science:
- Environmental Science
- Materials Science
- Chemical Engineering
Background:
- Antibiotic contamination in wastewater poses a significant environmental and health risk.
- Effective removal of antibiotics like amoxicillin (AMX) is crucial for wastewater treatment.
- Nanofiltration (NF) membranes offer a promising technology for pollutant removal.
Purpose of the Study:
- To investigate the performance of a self-made NF membrane for amoxicillin (AMX) removal from wastewater.
- To evaluate the impact of operating conditions (pH, concentration, pressure, temperature) on membrane performance.
- To characterize the self-made NF membrane's properties.
Main Methods:
- Fabrication of a Polyethersulfone (PES)/Polyvinylpyrrolidone (PVP) NF membrane modified with Brij®58 surfactant.
- Characterization of the membrane using water contact angle, zeta potential, ATR-FTIR, and SEM.
- Testing AMX removal efficiency and permeation flux under varying operating parameters.
Main Results:
- The self-made NF membrane achieved AMX rejection rates between 56.49% and 99.09%.
- Permeation flux ranged from 15.14 L/m²h to 110.29 L/m²h.
- AMX rejection decreased with increasing initial feed concentration; pH, pressure, and temperature had minimal effects.
- Optimal removal was observed at pH 9.0, 298 K, 2 MPa, and 20 ppm initial AMX concentration.
Conclusions:
- The self-made NF membrane demonstrates significant potential for amoxicillin removal from wastewater.
- Performance is highly dependent on initial feed concentration, with better results at lower concentrations.
- The developed membrane is recommended for effective AMX removal in wastewater treatment applications.
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