Enhanced catalytic activity toward O₂ reduction on Pt-modified La₁-xSrxCo₁-yFeyO₃-δ cathode: a combination study of...

Using the first-principles calculation and the electronic conductivity relaxation (ECR) experimental technique, we investigated the adsorption and dissociation behaviors of O2 on Pt-modified La0.625Sr0.375Co0.25Fe0.75O3-δ (LSCF) surface. Toward the O2 reduction, the calculation results show that the perfect LSCF (100) surface is catalytically less active than both the defective (100) surface and the perfect (110) surface. O2 molecule can weakly adsorb on the perfect LSCF (100) surface with a small adsorption energy of about -0.30 eV, but the dissociation energy barrier of the O2 molecule is about 1.33-1.43 eV. Doping of Pt cluster on the LSCF (100) surface can remarkably enhance its catalytic activity. The adsorption energies of O2 molecules become -1.16 and -1.89 eV for the interfacial Feint site and the Ptbri bridge site of Pt4-cluster, respectively. Meanwhile, the dissociation energy barriers are reduced to 0.37 and 0.53 eV, respectively. The migration energy barrier of the dissociated oxygen from the interfacial Pt to the LSCF surface is 0.66 eV, and it is 2.58 eV from the top site of the Pt cluster to the interfacial Pt site, suggesting that it is extremely difficult for oxygen to migrate over the Pt cluster. The Bader charge analysis results further indicate that the charges transferring from Pt cluster to LSCF surface promote the adsorption and dissociation of O2 molecules. Experimentally, a dramatic decrease of the surface oxygen exchange relaxation time was observed on Pt-modified LSCF cathode, with a chemical surface exchange coefficient increased from 6.05 × 10(-5) cm/s of the bare LSCF cathode to 4.04 × 10(-4) cm/s of the Pt-modified LSCF cathode, agreeing very well with our theoretical predictions.