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Updated: Apr 20, 2026

Evaluation of the Curing of Adhesive Systems by Rheological and Thermal Testing
Published on: July 3, 2020
Pressure-Sensitive Adhesives under the Influence of Relative Humidity: Inner Structure and Failure Mechanisms
Markus Schindler1, Manuel Koller1, Peter Müller-Buschbaum1
1Physik-Department, Lehrstuhl für Funktionelle Materialien, Technische Universität München, James-Franck-Strasse 1, 85748 Garching, Germany.
Abstract:
Model pressure-sensitive adhesive (PSA) films of the statistical copolymer P(EHA-stat-20MMA), which comprises 80% ethylhexyl acrylate (EHA) and 20% methyl methacrylate (MMA), are studied. The PSA films are stored under different relative humidities from <2% to 96% for 24 h and subsequently investigated concerning the near-surface composition profile by measuring X-ray reflectivity (XRR) and tack performance. For both types of measurements, special custom-made sample environments are used, which ensure constant temperature and relative humidity during the XRR and tack measurements. Different failure mechanisms of the adhesive bond are found by adjusting the relative humidity. XRR measurements evidence enrichment layers in vicinity to and at the surface depending on the provided relative humidity during the postproduction treatment, which also influence the tack performance. This finding is supported by tack measurements using punches with different roughness.
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