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Published on: September 5, 2018
Stabilization of Cu2O nanoparticles on a 2D metal-organic framework for catalytic Huisgen 1,3-dipolar cycloaddition
Kolleboyina Jayaramulu1, Venkata M Suresh, Tapas Kumar Maji
1Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560064, India. tmaji@jncasr.ac.in.
Abstract:
We report a simple methodology for the stabilization of Cu2O nanoparticles of size 2-4 nm on the polar pore surface of a 2D metal-organic framework, {[Zn(Himdc)(bipy)0.5]·DMF} (1). For the first time, a Cu2O@1a (1a: desolvated 1) composite has been utilized as a recyclable catalyst for the Huisgen 1,3-dipolar cycloaddition reaction of terminal alkynes and aliphatic/aromatic azides for the synthesis of 1,2,3-triazoles.
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