Related Experiment Video
Updated: Apr 20, 2026
![The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
{Sn10 [Si(SiMe3 )3 ]4 }(2-) : A highly reactive metalloid tin cluster with an open ligand shell
Claudio Schrenk1, Florian Winter, Rainer Pöttgen
1Faculty of Science, Institute of Inorganic Chemistry, University Tübingen, Auf der Morgenstelle 18, 72076 Tübingen (Germany), Fax: (+49) 7071-29-2436.
Abstract:
The reaction of a Sn(I) Cl solution with LiSi(SiMe3 )3 gave the anionic metalloid tin cluster {Sn10 [Si(SiMe3 )3 ]4 }(2-) (7) in good yield. The arrangement of the ten tin atoms in the cluster core can be described as a distorted centaur polyhedron. Quantum chemical calculations suggest that there are 26 bonding electrons in the cluster core, which may be described as an arachno cluster in agreement with Wade's rules. NMR and mass spectrometric investigations showed that 7 is highly reactive, which may be due to the open ligand shell. The easily available tin atoms in 7 thereby open the door to further subsequent reactions, in which 7 may act as a building block to larger cluster aggregates.
Related Concept Videos
Valence Bond Theory
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Properties of Transition Metals
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than...

