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Updated: Apr 20, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Assembly of metal-organic polyhedra into highly porous frameworks for ethene delivery
Ulrich Stoeck1, Irena Senkovska, Volodymyr Bon
1Department of Inorganic Chemistry, Technische Universität Dresden, Bergstraße 66, 01062 Dresden, Germany. Stefan.Kaskel@chemie.tu-dresden.de.
Abstract:
Two new mesoporous metal-organic frameworks (DUT-75 and DUT-76) with exceptional ethene uptake were obtained using carbazole dicarboxylate based metal-organic polyhedra as supermolecular building blocks. The compounds have a total pore volume of 1.84 and 3.25 cm(3) g(-1) and a specific BET surface area of 4081 and 6344 m(2) g(-1), respectively, and high gas uptake at room temperature and high pressure.
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