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Updated: Apr 20, 2026

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Speciation and Bioavailability Measurements of Environmental Plutonium Using Diffusion in Thin Films
Published on: November 9, 2015
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Elemental composition in sealed plutonium-beryllium neutron sources.
N Xu1, K Kuhn1, D Gallimore1
1Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
Summary
Five plutonium-beryllium (PuBe) neutron sources were analyzed using destructive chemical methods. This study developed a dissolution technique for accurate plutonium (Pu) and beryllium (Be) quantification for material disposition.
Area of Science:
- Nuclear Chemistry
- Analytical Chemistry
- Materials Science
Background:
- Plutonium-beryllium (PuBe) neutron sources are critical for various applications.
- Accurate characterization of PuBe materials is essential for safe handling and disposition.
- Existing analytical methods may require refinement for complex alloy matrices.
Purpose of the Study:
- To develop and validate a dissolution method for PuBe alloys.
- To quantitatively determine plutonium (Pu) and beryllium (Be) content in disused neutron sources.
- To analyze trace elemental variations among different PuBe sources.
Main Methods:
- Disassembly of five sealed PuBe neutron sources.
- Development of a chemical dissolution procedure for PuBe alloys.
- Quantitative analysis using inductively coupled plasma mass spectrometry (ICP-MS) for trace elements and beryllium (Be).
- Quantification of beryllium (Be) using inductively coupled plasma atomic emission spectrometry (ICP-AES).
- Plutonium (Pu) assay via an electrochemical method.
Main Results:
- A robust dissolution method for PuBe alloys was successfully established.
- Quantitative data for plutonium (Pu) and beryllium (Be) were obtained for disposition purposes.
- Trace elemental compositions varied across the five analyzed PuBe sources, indicating differences in manufacturing or material history.
Conclusions:
- The developed dissolution and analytical methods are suitable for the disposition of PuBe neutron sources.
- Understanding trace element variations is important for source characterization and management.
- This work provides critical data for the safe and effective management of radioactive materials.
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