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Updated: Apr 19, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Temperature gradients in equilibrium: Small microcanonical systems in an external field
Alberto Salazar1, Hernán Larralde2, François Leyvraz2
1Instituto de Ciencias Físicas, UNAM, Apartado Postal 48-3, Codigo Postal 62251, Cuernavaca, Morelos, Mexico and Instituut voor Theoretische Fysica, KU Leuven, Leuven, Belgium.
Abstract:
We consider the statistical mechanics of a small gaseous system subject to a constant external field. As is well known, in the canonical ensemble, that the system (i) obeys a barometric formula for the density profile, and (ii) the kinetic temperature is independent of height, even when the system is small. We show here that in the microcanonical ensemble the kinetic temperature of the particles affected by the field is not constant with height, but that rather, generally speaking, it decreases with a gradient of order 1/N. Even more, if we have a mixture of two species, one which is influenced by the field and the other which is not, we find that the two species' kinetic temperatures are generally different, even at the same height. These facts are shown in detail by studying a simple mechanical model: a Lorentz Gas where particles and spinning disks interact and the particles are subjected to a constant external force. In the microcanonical ensemble, the kinetic temperature of the particles is indeed found to vary with height; the disks' kinetic temperature, on the other hand, is height-independent, and thus, differs from that of the particles with which they interact.
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