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Rapid, nondestructive denim fiber bundle characterization using luminescence hyperspectral image analysis.
Randi E Deuro1, Kristen M Leiker, Yanhui Wang
1Department of Chemistry, Natural Sciences Complex, University at Buffalo, State University of New York, Buffalo, NY 14260-3000 USA.
Luminescence-based hyperspectral imaging (LHSI) rapidly discriminates denim fiber bundles. Nitromethane quenching further enhances this discrimination by revealing differences in dye molecule accessibility.
Area of Science:
- Analytical Chemistry
- Materials Science
- Spectroscopy
Background:
- Denim fiber identification is crucial for quality control and authentication.
- Traditional methods for fiber analysis can be time-consuming and destructive.
Purpose of the Study:
- To evaluate luminescence-based hyperspectral imaging (LHSI) for discriminating denim fiber bundles.
- To investigate nitromethane (CH3NO2) quenching for improved discrimination and to determine its mechanism.
Main Methods:
- Luminescence spectra (450-850 nm) and images of denim fiber bundles were acquired using 325 nm or 405 nm excitation.
- Data were collected rapidly (<5 s) and analyzed using principal component analysis (PCA) and RGB histograms.
- Nitromethane (CH3NO2) quenching was employed to probe dye molecule accessibility.
Main Results:
- LHSI successfully achieved rapid and unique discrimination of all tested denim fiber bundle types.
- The non-destructive LHSI technique significantly reduced sample preparation time.
- Quenching data indicated varying accessibility of dye molecules to CH3NO2 across different fiber bundles.
Conclusions:
- LHSI is a powerful, rapid, and non-destructive technique for denim fiber bundle identification.
- Nitromethane quenching provides insights into the molecular structure and accessibility of dyes within denim fibers.
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