Related Experiment Video
Updated: Apr 19, 2026

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Creation of ultracold ^{87}Rb^{133}Cs molecules in the rovibrational ground state
Peter K Molony1, Philip D Gregory1, Zhonghua Ji1
1Department of Physics, Joint Quantum Centre (JQC) Durham-Newcastle, Durham University, South Road, Durham DH1 3LE, United Kingdom.
Abstract:
We report the creation of a sample of over 1000 ultracold ^{87}Rb^{133}Cs molecules in the lowest rovibrational ground state, from an atomic mixture of ^{87}Rb and ^{133}Cs, by magnetoassociation on an interspecies Feshbach resonance followed by stimulated Raman adiabatic passage (STIRAP). We measure the binding energy of the RbCs molecule to be hc×3811.576(1) cm^{-1} and the |v^{''}=0,J^{''}=0⟩ to |v^{''}=0,J^{''}=2⟩ splitting to be h×2940.09(6) MHz. Stark spectroscopy of the rovibrational ground state yields an electric dipole moment of 1.225(3)(8) D, where the values in parentheses are the statistical and systematic uncertainties, respectively. We can access a space-fixed dipole moment of 0.355(2)(4) D, which is substantially higher than in previous work.
Related Concept Videos
Atomic Nuclei: Nuclear Spin State Population Distribution
UV–Vis Spectroscopy: Molecular Electronic Transitions
Deactivation Processes: Jablonski Diagram
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution
Atomic Nuclei: Nuclear Relaxation Processes
Atomic Spectroscopy: Effects of Temperature
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature...

