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Post metalation of solvothermally grown electroactive porphyrin metal-organic framework thin films
Chung-Wei Kung1, Ting-Hsiang Chang, Li-Yao Chou
1Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan. kcho@ntu.edu.tw.
Chemical Communications (Cambridge, England)
|January 8, 2015
Abstract:
Uniform thin films of a metal-organic framework, which is constructed from free-base porphyrin linkers and hexa-zirconium nodes (MOF-525), are solvothermally grown on conducting substrates. Subsequently, solvothermal post metalations are employed to prepare the Zn-MOF-525 and Co-MOF-525 thin films. All the thin films are electroactive in aqueous media.
