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Updated: Apr 18, 2026
Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
Synthesis and properties of the strained alkene perfluorobicyclo[2.2.0]hex-1(4)-ene
Christopher P Junk1, Yigang He, Yin Zhang
1Department of Chemistry, Dartmouth College , Hanover, New Hampshire 03755, United States.
Abstract:
The title fluoroalkene has been generated by dehalogenation of dibromide and diiodide precursors and trapped in situ. retro-Diels-Alder reaction of its adduct with N-benzylpyrrole has made the alkene available in high yield and purity. In sharp contrast to its extremely labile hydrocarbon counterpart, the fluoroalkene is very stable yet highly reactive. Its characterization includes its electron affinity, photoelectron spectrum, and the previously reported structure determination by electron diffraction.
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