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Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR
K Ackermann1, A Giannoulis, D B Cordes
1EaStCHEM School of Chemistry, Biomedical Sciences Research Complex and Centre of Magnetic Resonance, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK. beb2@st-andrews.ac.uk.
Abstract:
Pulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecule model system for tuneable dimerisation.
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