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Updated: Apr 18, 2026

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Flexible confinement leads to multiple relaxation regimes in glassy colloidal liquids
Ian Williams1, Erdal C Oğuz2, Paul Bartlett3
1H.H. Wills Physics Laboratory, Tyndall Ave., Bristol BS8 1TL, United Kingdom.
Abstract:
Understanding relaxation of supercooled fluids is a major challenge and confining such systems can lead to bewildering behaviour. Here, we exploit an optically confined colloidal model system in which we use reduced pressure as a control parameter. The dynamics of the system are "Arrhenius" at low and moderate pressure, but at higher pressures relaxation is faster than expected. We associate this faster relaxation with a decrease in density adjacent to the confining boundary due to local ordering in the system enabled by the flexible wall.
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