Disinfection of raw wastewater and activated sludge effluent using Fenton like reagent

Water shortage problems have led to find either new water resources or improve wastewater treatment technologies in order to reuse. Due to less performance of previous units in microbial removal, disinfection has become a necessary step in wastewater treatment plants. In the present study performance of hydrogen peroxide (HP) and modified Fenton's reagent (HP + Cu(++)) was considered for the disinfection of raw wastewater (RW) and activated sludge effluent (ASE).

Plastic containers of 10-liter volume each were used for RW and ASE sampling. Microbiological analyses of the RW and ASE were performed in triplicate; before and after the disinfection process. Fecal coliforms were analyzed by the direct (without enrichment) multiple fermentation tube procedure.

The results showed that using HP alone did not have any significant disinfection capability. In RW and ASE, the highest dose used in this study could reduce fecal coliforms (FC)s by only 1.54 and 1.16 log-inactivation, respectively. However, Maximum removal efficiency of modified Fenton in RW and ASE was 4.63 and 3.41 log-inactivation, respectively. The results suggested that Cu(++) ions used in combination with H2O2 produced very rigorous synergistic effect, and HP disinfection capacity increased significantly.

Hydrogen peroxide, when applied alone, was not successful in disinfecting of either RW or ASE, and neither the WHO guideline nor the Iranian standard could be met. However, modified Fenton showed very significant disinfection potential and could reduce FCs under World Health Organization (WHO) guideline and Iranian national standard for agricultural irrigation.