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Updated: Apr 18, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
Structure, photochemistry and magnetic properties of tetrahydrogenated Schiff base chromium(III) complexes
Bin Liu1, Jie Chai1, SiSi Feng1
1Institute of Molecular Science, Key Laboratory of Chemical Biology of Molecular Engineering of Education Ministry, Shanxi University, Taiyuan 030006, China.
Abstract:
Four mononuclear chromium(III) complexes [Cr(L(1))(en)]Br0.3Cl0.7 (1), [Cr(L(1))(pr)]Cl (2), [Cr(L(2))(en)]ClO4 (3), [Cr(L(2))(pr)]Cl (4) along with one dinuclear μ-methoxo [Cr(μ-OMe)(L1)]2 (5) were synthesized (en=1,2-ethanediamine, pr=1,3-diaminopropane H2L(1)=Tetrahydrosalen=H2[H4]salen=N,N'-bis(2-hydroxybenzyl)-1,2-ethanediamine, H2L(2)=Tetrahydrosalpr=H2[H4]salpr=N,N'-bis(2-hydroxybenzyl)-1,3-diaminopropane). The competitive reactions in the presence of EDTA were carried out and the first-order rate constants k(1)=(5.2±0.2)×10(-3) h(-1)
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