Disordered solids without well-defined transverse phonons: the nature of hard-sphere glasses

We probe the Ioffe-Regel limits of glasses with repulsions near the zero-temperature jamming transition by calculating the dynamical structure factors. The Ioffe-Regel limit (frequency) is reached when the phonon wavelength is comparable to the mean free path, beyond which phonons are no longer well defined. At zero temperature, the transverse Ioffe-Regel frequency vanishes at the jamming transition with a diverging length, but the longitudinal one does not, which excludes the existence of a diverging length associated with the longitudinal excitations. At low temperatures, the transverse and longitudinal Ioffe-Regel frequencies approach zero at the jamminglike transition and glass transition, respectively. As a consequence, glasses between the glass transition and the jamminglike transition, which are hard-sphere glasses in the low temperature limit, can only carry well-defined longitudinal phonons and have an opposite pressure dependence of the ratio of the shear modulus to the bulk modulus from glasses beyond the jamminglike transition.