Related Experiment Video
Updated: Apr 17, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
Theoretical study of interactions between electron-deficient arenes and coinage metal anions
1School of Chemistry & Chemical Engineering, Qujing Normal University, Qujing, 655011, Yunnan, China, chenyishan916@163.com.
Abstract:
The binding behavior of coinage metal anions with some electron-deficient arenes has been investigated by MP2 calculations, and the character of interactions in these complexes has been examined by NBO analysis. The results indicate that coinage metal anions can interact with electron-deficient arenes to form anion-π, strong σ-type and hydrogen-bonding complexes. The σ-type structure is the global minimum for triazine, trifluorotriazine, hexafluorobenzene and tricyanobenzene, and the hydrogen-bonding structure is the global minimum for trifluorobenzene. There exist some differences in the stability of anion-π complexes for coinage metal anions: the anion-π complexes of Au(-) are minima expect for triazine complex; the anion-π complexes of Ag(-) are minima expect for tricyanobenzene complex; and the anion-π complexes of Cu(-) are not minima expect for trifluorobenzene complex. The binding strength of anion-π and hydrogen-bonding complexes for Au(-) is larger than that for Ag(-) and Cu(-), but the binding strength of σ complex displays a different sequence: Cu(-) > Au(-) > Ag(-). The binding behavior of coinage metal anions is more similar to that of F(-) than that of Cl(-) and Br(-). The relaxed potential energy surface scans for some selected systems have been performed to help understand the interactions between coinage metal anions with electron-deficient arenes.
More Related Videos
Related Concept Videos
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Complexation Equilibria: The Chelate Effect
Valence Bond Theory
Complexation Equilibria: Factors Influencing Stability of Complexes
Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly,...
Formation of Complex Ions

