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Multiply associating electrolytes in the binding mean spherical approximation: thermodynamic properties and

O Bernard1, J Torres-Arenas2, J-P Simonin1

  • 1Laboratoire Physicochimie des Electrolytes, Colloïdes et Sciences Analytiques, PECSA (UMR CNRS 7195), Université P. M. Curie, Case 51, 4 Place Jussieu, 75252 Paris Cedex 05, France.

The Journal of Chemical Physics
|February 12, 2015
PubMed
Summary

This study introduces the binding mean spherical approximation (BiMSA) to model ionic solutions with multiple associations. The BiMSA model provides accurate analytical expressions for thermodynamic properties and ion complexation in these solutions.

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