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Related Concept Videos

¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

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The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene...
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Determination of the Excitation and Coupling Rates Between Light Emitters and Surface Plasmon Polaritons
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Exploring plasmonic coupling in hole-cap arrays.

Thomas M Schmidt1, Maj Frederiksen1, Vladimir Bochenkov2

  • 1Interdisciplinary Nanoscience Center (iNANO), Aarhus University, Gustav Wieds Vej 14, 8000 Aarhus, Denmark.

Beilstein Journal of Nanotechnology
|February 12, 2015
PubMed
Summary
This summary is machine-generated.

Plasmonic coupling between gold caps and hole arrays was studied. Close proximity enables strong coupling to surface plasmon polariton and resonance modes, revealing field distribution details.

Keywords:
SRO hole arrayscapscolloidal lithographyhybridizationlocalized surface plasmon resonancenear field

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Area of Science:

  • Nanophotonics
  • Plasmonics
  • Materials Science

Background:

  • Surface plasmon polaritons (SPPs) and localized surface plasmon resonances (LSPRs) are crucial for nanoscale optical phenomena.
  • Controlling the interaction between different plasmonic structures is key to designing advanced optical devices.

Purpose of the Study:

  • To investigate the plasmonic coupling between gold caps and gold hole arrays in thin films.
  • To understand how vertical spacing influences the coupling dynamics and resulting optical properties.

Main Methods:

  • Experimental investigation using sparse colloidal lithography and thermal treatment to control spacing.
  • Finite-difference time-domain (FDTD) simulations for theoretical analysis.
  • Optical spectroscopy to characterize the plasmonic responses.

Main Results:

  • Strong plasmonic coupling observed between gold caps and hole arrays when in close proximity.
  • Coupling affects both Bloch Wave-surface plasmon polariton (BW-SPP) and localized surface plasmon resonance (LSPR) modes.
  • Detailed field distributions were revealed through experimental and simulation data.

Conclusions:

  • Close proximity is essential for significant plasmonic coupling between caps and hole arrays.
  • The studied structures exhibit complex coupling behaviors with tunable optical properties.
  • These findings offer insights into fabricating and utilizing coupled plasmonic systems.