Bipolar electrochemical method for dynamic in situ control of single metal nanowire growth

Fabrication plays a key role in determining the unique electrical, optical, and catalytic properties of metal nanowires. Here we present a bipolar electrochemical method for dynamically monitoring and controlling the rate of single metal nanowire growth in situ without a direct electrical connection. Solutions of a metal precursor and a reducing agent are placed on either side of a silica nanochannel, and a pair of electrodes is used to apply a tunable electric potential across the channel. Metal nanowire growth is initiated by chemical reduction when the two solutions meet and continues until the nanochannel is blocked by the formation of a short metal wire segment. Further growth is driven by a bipolar electrochemical mechanism which enables the reduction of metal precursor ions at one end of the nanowire and the oxidation of the reducing agent at the other. The growth rate is monitored in real time by simultaneously recording both the faradaic current and optical microscope video and can be adjusted accordingly by changing the applied electric potential. The resulting nanowire is solid, electrically insulated, and can be used as a bipolar nanoelectrode. This technique can be extended to other electrochemical systems, as well, and provides a confined reaction space for studying the dynamics of any process that can be optically or electrically monitored.